LPO-过氧化二月桂酰--CAS.105-74-8
公司: | 山东海京新材料有限公司 |
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产品介绍
商品名称:LPO
中文名称:过氧化二月桂酰
化学名称:过氧化二月桂酰
分子式:C24H46O4
分子量:398.6
理论活性氧含量:4.01%
CAS号:105-74-8
Einecs:203-326-3
主要分解产物: CO2、月桂酸酯
指标:
半衰期:
0.1小时:99℃
1小时:79℃
10小时:61℃
热稳定性数据:
自加速分解温度(SADT):50℃
危急温度(Tem):45℃
控制温度(Tc):--
贮存温度(Tsmax):--/30 ℃
技术标准:
外观:白色粉状或片状固体
含量:≥99.0%
用途:本产品是乙烯、苯乙烯、氯乙烯、偏二氯乙烯、丙烯酸酯和甲基丙烯酸酯和聚合引发剂。
包装:
LPO的标准包装是净重25公斤的纸板桶,或瓦楞纸箱内装四个5公斤塑料袋,净重20公斤。也可按用户的要求的规格包装。
LPO为D类固体有机过氧化物,货物分类:5.2,联合国编号:3106,二类危险货物包装.
注意事项:
(1) 远离火种、明火和热源。
(2) 避免接触还原剂(如胺类)、酸、碱和重金属化合物(如促进剂、金属皂等)
(3) 请参照本产品的数据表(MSDS)。
用途:
1. 氯乙烯的聚合:
LPO广泛地应用于水相悬浮聚合和本体聚合反应中,聚合的温度范围为60-75℃,很多情况下,LPO和其它高活性的过氧化物复配使用,例如,过氧化二碳酸酯类(过氧化二碳酸双-4-叔丁基环已烷),或过氧酯类(过氧化新癸酸-1,1,3,3-四甲基丁酯),可以增加其反应活性。
2. 乙烯的聚合:
LPO使用于高压聚乙烯的聚合引发,由于它的溶解性较差,在很多情况下被过氧化异壬酰所取代,但是LPO的优点是它可在常温下保存。
3. 丙烯酸酯和甲基丙烯酸酯的聚合:
LPO也可以用于丙烯酸酯的聚合反应,聚合反应温度为60-90℃。
4. ABS树脂的聚合引发剂:
LPO同时也是ABS聚合反应的重要引发剂,它和1,1-二叔丁基过氧化-3,3,5-三甲基环已烷(LQ-CH335)复配使用,具有很好的引发效果。
Product name:LPO
English name:Dilauroyl peroxide
Chemical name: lauroyl peroxide
Molecular formula:C24H46O4
Molecular weight:398.6
Theoretical active oxygen content:4.01%
CAS.:105-74-8
Einecs:203-326-3
Main decomposition products: CO2, laurate
Safety indicators:
Half life (measured in chlorobenzene solution):
0.1 hour: 99 ℃
1 hour: 79 ℃
10 hours: 61 ℃
Thermal stability data:
Self accelerating decomposition temperature (SADT): 50 ℃
Emergency temperature (Tem): 45 ℃
Control temperature (Tc):--
Storage temperature (Tsmax): --/30 ℃
Technical standards:
Appearance: White powder or flake solid
Content:≥99.0%
Usage: This product is ethylene, styrene, vinyl chloride, vinylidene chloride, acrylate, methacrylate, and polymerization initiator.
packing:
The standard packaging for LPO is a cardboard drum with a net weight of 25 kilograms, or a corrugated cardboard box containing four plastic bags with a net weight of 20 kilograms. It can also be packaged according to the specifications requested by the user.
LPO is a Class D solid organic peroxide, cargo classification: 5.2, UN number: 3106, packaging for Class II dangerous goods
Safety precautions:
(1) Keep away from sparks, open flames, and heat sources.
(2) Avoid contact with reducing agents (such as amines), acids, bases, and heavy metal compounds (such as accelerators, metal soaps, etc.)
(3) Please refer to the Safety Data Sheet (MSDS) of this product.
Purpose:
1. Polymerization of vinyl chloride:
LPO is widely used in aqueous suspension polymerization and bulk polymerization reactions, with polymerization temperatures ranging from 60 to 75 ℃. In many cases, LPO can be used in combination with other highly active peroxides, such as peroxydicarbonate esters (peroxydicarbonate di-4-tert-butyl cyclohexane) or peroxyesters (peroxyneodecanoic acid-1,1,3,3-tetramethylbutyl ester), which can increase their reaction activity.
2. Ethylene polymerization:
LPO is used for polymerization initiation of high-pressure polyethylene, and due to its poor solubility, it is often replaced by isononyl peroxide. However, the biggest advantage of LPO is that it can be stored at room temperature.
3. Polymerization of acrylate and methacrylate:
LPO can also be used for the polymerization reaction of acrylic esters, with a polymerization temperature of 60-90 ℃
4. Polymerization initiator for ABS resin:
LPO is also an important initiator for ABS polymerization reaction. It is used in combination with 1,1-ditert-butylperoxy-3,3,5-trimethylcyclohexane (LQ-CH335) and has a good initiating effect.